English

高尾賢一

有機合成化学研究室・ 教授・博士(工学)
内線 : 42367 部屋番号 : 23 棟 510A 号室
E-mail : takao@applc.keio.ac.jp

略歴

研究内容

発表論文(代表的な論文を抜粋)

  1. Ken-ichi Takao, Hiroyuki Yasui, Shun Yamamoto, Daisuke Sasaki, Soujiro Kawasaki, Gohshi Watanabe, and Kin-ichi Tadano,  “Asymmetric Total Syntheses of (+)-Mycoepoxydiene and Related Natural Product (–)-1893A: Application of One-Pot Ring-Opening/Cross/Ring-Closing Metathesis to Construct their 9-Oxabicyclo[4.2.1]nona-2,4-diene Skeleton” J. Org. Chem., 69, 8789 (2004)
  2. Ken-ichi Takao, Ryosuke Munakata, and Kin-ichi Tadano, “Recent Advances in Natural Product Synthesis by Using Intramolecular Diels-Alder Reactions” Chem. Rev., 105, 4779 (2005)
  3. Ken-ichi Takao, Nobuhiko Hayakawa, Reo Yamada, Taro Yamaguchi, Urara Morita, Soujiro Kawasaki, and Kin-ichi Tadano,  “Total Synthesis of (–)-Pestalotiopsin A”  Angew. Chem. Int. Ed., 47, 3426 (2008)
  4. Ken-ichi Takao, Nobuhiko Hayakawa, Reo Yamada, Taro Yamaguchi, Hiroshi Saegusa, Masatoshi Uchida, Suguru Samejima, and Kin-ichi Tadano,  “Total Syntheses of (+)- and (–)-Pestalotiopsin A”  J. Org. Chem., 74, 6452 (2009) Featured Article
  5. Ken-ichi Takao, Shu Sakamoto, Marianne Ayaka Touati, Yusuke Kusakawa, and Kin-ichi Tadano,  “Asymmetric Construction of All-Carbon Quaternary Stereocenter by Chiral-Auxiliary-Mediated Claisen Rearrangement and Total Synthesis of (+)-Bakuchiol”  Molecules, 17, 13330 (2012)
  6. Ken-ichi Takao, Ryuki Nanamiya, Yuuki Fukushima, Ayumi Namba, Keisuke Yoshida, and Kin-ichi Tadano,  “Total Synthesis of (+)-Clavilactone A and (–)-Clavilactone B by Ring-Opening/Ring-Closing Metathesis”  Org. Lett., 15, 5582 (2013)
  7. Ken-ichi Takao, Kohei Tsunoda, Takuya Kurisu, Akihiro Sakama, Yoshiyasu Nishimura, Keisuke Yoshida, and Kin-ichi Tadano,  “Total Synthesis of (+)-Vibsanin A”  Org. Lett., 17, 756 (2015)
  8. Ken-ichi Takao, Shuji Noguchi, Shu Sakamoto, Mizuki Kimura, Keisuke Yoshida, and Kin-ichi Tadano,  “Total Synthesis of (+)-Cytosporolide A via a Biomimetic Hetero-Diels-Alder Reaction”  J. Am. Chem. Soc., 137, 15971 (2015)
  9. Ken-ichi Takao, Ryuichi Nemoto, Kento Mori, Ayumi Namba, Keisuke Yoshida, and Akihiro Ogura,  “Total Synthesis and Structural Revision of Clavilactone D”  Chem. Eur. J., 23, 3828 (2017)

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